what price oil?

  1. 3,816 Posts.
    There are a few correcting factors which come into play with high oil prices. The most important historically comes from new
    discoveries. Bush intends to address this by opening up large areas of the US to oil exploration should he be elected. Another is
    the development of alternative fuel sources, such as shale oil, tar sands, and renewables such as bodilesel and bioethanol. These
    alternatives become closer to being viable during sustained high prices. Should they become viable, they will effectively cap the
    oil price ever more. This is why the Arabs want a lower oil price: high enough to be profitable, but low enough to stifle the
    competition. So Chinese and Indian demand might be doing the world a big favour.

    The oil boom still has years to run imo, but the following - posted by thurlow some time ago - makes a good read.

    Billy

    http://www.unh.edu/p2/biodiesel/article_alge.html

    Widescale Biodiesel Production from Algae
    Michael Briggs, University of New Hampshire, Physics Department

    (revised August 2004)

    As more evidence comes out daily of the ties between the leaders of petroleum producing countries and terrorists (not to mention the
    human rights abuses in their own countries), the incentive for finding an alternative to petroleum rises higher and higher. The
    environmental problems of petroleum have finally been surpassed by the strategic weakness of being dependent on a fuel that can only
    be purchased from tyrants. The economic strain on our country resulting from the $100-150 billion we spend every year buying oil
    from other nations, combined with the occasional need to use military might to protect and secure oil reserves our economy depends
    on just makes matters worse (and using military might for that purpose just adds to the anti-American sentiment that gives rise to
    terrorism). Clearly, developing alternatives to oil should be one of our nation's highest priorities.

    In the United States, oil is primarily used for transportation - roughly two-thirds of all oil use, in fact. So, developing an
    alternative means of powering our cars, trucks, and buses would go a long way towards weaning us, and the world, off of oil. While
    the so-called "hydrogen economy" receives a lot of attention in the media, there are several very serious problems with using
    hydrogen as an automotive fuel. For automobiles, the best alternative at present is clearly biodiesel, a fuel that can be used in
    existing diesel engines with no changes, and is made from vegetable oils or animal fats rather than petroleum.

    In this paper, I will first examine the possibilities of producing biodiesel on the scale necessary to replace all petroleum
    transportation fuels in the U.S.

    I. How much biodiesel?

    First, we need to understand exactly how much biodiesel would be needed to replace all petroleum transportation fuels. So, we need
    to start with how much petroleum is currently used for that purpose. Per the Department of Energy's statistics, each year the US
    consumes roughly 60 billion gallons of petroleum diesel and 120 billion gallons of gasoline. First, we need to realize that
    spark-ignition engines that run on gasoline are generally about 40% less efficient than diesel engines. So, if all spark-ignition
    engines are gradually replaced with compression-ignition (Diesel) engines for running biodiesel, we wouldn't need 120 billion
    gallons of biodiesel to replace that 120 billion gallons of gasoline. To be conservative, we will assume that the average gasoline
    engine is 35% less efficient, so we'd need 35% less diesel fuel to replace that gasoline. That would work out to 78 billion gallons
    of diesel fuel. Combine that with the 60 billion gallons of diesel already used, for a total of 138 billion gallons. Now, biodiesel
    is about 5-8% less energy dense than petroleum diesel, but its greater lubricity and more complete combustion offset that somewhat,
    leading to an overall fuel efficiency about 2% less than petroleum diesel. So, we'd need about 2% more than that 138 billion
    gallons, or 140.8 billion gallons of biodiesel. So, this figure is based on vehicles equivalent to those in use today, but with
    compression-ignition (Diesel) engines running on biodiesel, rather than a mix of petroleum diesel and gasoline. Combined
    diesel-electric hybrids in wide use, as well as fewer people driving large SUVs when they don't need such a vehicle would of course
    bring this number down considerably, but for now we'll just stick with this figure. (note - my point here is not to claim that
    conservation is not worthwhile, rather to strictly look at the issue of replacing our current use of fuel with biodiesel - to see
    how achievable that is). I would like to point out though that a preferable scenario would include a shift to diesel-electric
    hybrid vehicles (preferably with the ability to be recharged and drive purely on electric power for a short range, perhaps 20-40
    miles, to provide the option of zero emissions for in-city driving), and with far fewer people buying 6-8,000 pound SUVs merely to
    commute to work in by themselves. Those changes could drastically reduce the amount of fuel required for our automotive
    transportation, and are technologically feasibly currently (see for example Chrysler's Dodge Intrepid ESX3, built under Clinton's
    PNGV program - a full-size diesel electric hybrid sedan that averaged 72 mpg in mixed driving 6, 7).

    One of the biggest advantages of biodiesel compared to many other alternative transportation fuels is that it can be used in
    existing diesel engines without modification, and can be blended in at any ratio with petroleum diesel. This completely eliminates
    the "chicken-and-egg" dilemma that other alternatives have, such as hydrogen powered fuel cells. For hydrogen vehicles, even when
    (and if) vehicle manufacturers eventually have production stage vehicles ready (which currently cost around $1 million each to
    make), nobody would buy them unless there was already a wide scale hydrogen fuel production and distribution system in place. But,
    no companies would be interested in building that wide scale hydrogen fuel production and distribution system until a significant
    number of fuel cell vehicles are on the road, so that consumers are ready to start using it. With a single hydrogen fuel pump
    costing roughly $1 million, installing just one at each of the 176,000 fuel stations across the US would cost $176 billion - a cost
    that can be completely avoided with liquid biofuels that can use our current infrastructure.

    With biodiesel, since the same engines can run on conventional petroleum diesel, manufacturers can comfortably produce diesel
    vehicles before biodiesel is available on a wide scale - as some manufacturers already are (the same can be said for flex-fuel
    vehicles capable of running on ethanol, gasoline, or any blend of the two). As biodiesel production continues to ramp up, it can go
    into the same fuel distribution infrastructure, just replacing petroleum diesel either wholly (as B100, or 100% biodiesel), or
    blended in with diesel. Not only does this eliminate the chicken-and-egg problem, making biodiesel a much more feasible alternative
    than hydrogen, but also eliminates the huge cost of revamping the nationwide fuel distribution infrastructure.

    II. Large scale production

    There are two steps that would need to be taken for producing biodiesel on a large scale - growing the feedstocks, and processing
    them into biodiesel. The main issue that is often contested is whether or not we would be able to grow enough crops to provide the
    vegetable oil (feedstock) for producing the amount of biodiesel that would be required to completely replace petroleum as a
    transportation fuel. So, that is the main issue that will be addressed here. The point of this article is not to argue that this
    approach is the only one that makes sense, or that we should ignore other options (there are some other very appealing options as
    well, and realistically it makes more sense for a combination of options to be used). Rather, the point is merely to look at one
    option for producing biodiesel, and see if it would be capable of meeting our needs.

    One of the important concerns about wide-scale development of biodiesel is if it would displace croplands currently used for food
    crops. In the US, roughly 450 million acres of land is used for growing crops, with the majority of that actually being used for
    producing animal feed for the meat industry. Another 580 million acres is used for grassland pasture and range, according to the
    USDA's Economic Research Service. This accounts for nearly half of the 2.3 billion acres within the US (only 3% of which, or 66
    million acres, is categorized as urban land). For any biofuel to succeed at replacing a large quantity of petroleum, the yield of
    fuel per acre needs to be as high as possible. At heart, biofuels are a form of solar energy, as plants use photosynthesis to
    convert solar energy into chemical energy stored in the form of oils, carbohydrates, proteins, etc.. The more efficient a
    particular plant is at converting that solar energy into chemical energy, the better it is from a biofuels perspective. Among the
    most photosynthetically efficient plants are various types of algaes.

    The Office of Fuels Development, a division of the Department of Energy, funded a program from 1978 through 1996 under the National
    Renewable Energy Laboratory known as the "Aquatic Species Program". The focus of this program was to investigate high-oil algaes
    that could be grown specifically for the purpose of wide scale biodiesel production1. The research began as a project looking into
    using quick-growing algae to sequester carbon in CO2 emissions from coal power plants. Noticing that some algae have very high oil
    content, the project shifted its focus to growing algae for another purpose - producing biodiesel. Some species of algae are
    ideally suited to biodiesel production due to their high oil content (some well over 50% oil), and extremely fast growth rates. From
    the results of the Aquatic Species Program2, algae farms would let us supply enough biodiesel to completely replace petroleum as a
    transportation fuel in the US (as well as its other main use - home heating oil) - but we first have to solve a few of the problems
    they encountered along the way.

    NREL's research focused on the development of algae farms in desert regions, using shallow saltwater pools for growing the algae.
    Using saltwater eliminates the need for desalination, but could lead to problems as far as salt build-up in bonds. Building the
    ponds in deserts also leads to problems of high evaporation rates. There are solutions to these problems, but for the purpose of
    this paper, we will focus instead on the potential such ponds can promise, ignoring for the moment the methods of addressing the
    solvable challenges remaining when the Aquatic Species Program at NREL ended.

    NREL's research showed that one quad (7.5 billion gallons) of biodiesel could be produced from 200,000 hectares of desert land
    (200,000 hectares is equivalent to 780 square miles, roughly 500,000 acres), if the remaining challenges are solved (as they will
    be, with several research groups and companies working towards it, including ours at UNH). In the previous section, we found that to
    replace all transportation fuels in the US, we would need 140.8 billion gallons of biodiesel, or roughly 19 quads (one quad is
    roughly 7.5 billion gallons of biodiesel). To produce that amount would require a land mass of almost 15,000 square miles. To put
    that in perspective, consider that the Sonora desert in the southwestern US comprises 120,000 square miles. Enough biodiesel to
    replace all petroleum transportation fuels could be grown in 15,000 square miles, or roughly nine percent of the area of the Sonora
    desert (note for clarification - I am not advocating putting 15,000 square miles of algae ponds in the Sonora desert. This
    hypothetical example is used strictly for the purpose of showing the scale of land required). That 15,000 square miles works out to
    roughly 9.5 million acres - far less than the 450 million acres currently used for crop farming in the US, and the over 500 million
    acres used as grazing land for farm animals.

    The algae farms would not all need to be built in the same location, of course (and should not for a variety of reasons). The case
    mentioned above of building it all in the Sonora desert is purely a hypothetical example to illustrate the amount of land required.
    It would be preferable to spread the algae production around the country, to lessen the cost and energy used in transporting the
    feedstocks. Algae farms could also be constructed to use waste streams (either human waste or animal waste from animal farms) as a
    food source, which would provide a beautiful way of spreading algae production around the country. Nutrients can also be extracted
    from the algae for the production of a fertilizer high in nitrogen and phosphorous. By using waste streams (agricultural, farm
    animal waste, and human sewage) as the nutrient source, these farms essentially also provide a means of recycling nutrients from
    fertilizer to food to waste and back to fertilizer. Extracting the nutrients from algae provides a far safer and cleaner method of
    doing this than spreading manure or wastewater treatment plant "bio-solids" on farmland.

    These projected yields of course depend on a variety of factors, sunlight levels in particular. The yield in North Dakota, for
    example, wouldn't be as good as the yield in California. Spreading the algae production around the country would result in more
    land being required than the projected 9.5 million acres, but the benefits from distributed production would outweigh the larger
    land requirement.

    III. Cost

    In "The Controlled Eutrophication process: Using Microalgae for CO2 Utilization and Agircultural Fertilizer Recycling"3, the authors
    estimated a cost per hectare of $40,000 for algal ponds. In their model, the algal ponds would be built around the Salton Sea (in
    the Sonora desert) feeding off of the agircultural waste streams that normally pollute the Salton Sea with over 10,000 tons of
    nitrogen and phosphate fertilizers each year. The estimate is based on fairly large ponds, 8 hectares in size each. To be
    conservative (since their estimate is fairly optimistic), we'll arbitrarily increase the cost per hectare by 100% as a margin of
    safety. That brings the cost per hectare to $80,000. Ponds equivalent to their design could be built around the country, using
    wastewater streams (human, animal, and agricultural) as feed sources. We found that at NREL's yield rates, 15,000 square miles (3.85
    million hectares) of algae ponds would be needed to replace all petroleum transportation fuels with biodiesel. At the cost of
    $80,000 per hectare, that would work out to roughly $308 billion to build the farms.

    The operating costs (including power consumption, labor, chemicals, and fixed capital costs (taxes, maintenance, insurance,
    depreciation, and return on investment) worked out to $12,000 per hectare. That would equate to $46.2 billion per year for all the
    algae farms, to yield all the oil feedstock necessary for the entire country. Compare that to the $100-150 billion the US spends
    each year just on purchasing crude oil from foreign countries, with all of that money leaving the US economy.

    These costs are based on the design used by NREL - the simple open-top raceway pond. Various approaches being examined by the
    research groups focusing on algae biodiesel range from being the same general system, to far more complicated systems. As a result,
    this cost analysis is very much just a general approximation. Some systems could be considerably more expensive, but could also see
    considerably higher yields, resulting in less land being required. How exactly the economics play out will hopefully be decided
    over the next few years as some of these groups research algal biodiesel bring their systems to commercialization status.

    IV. Other issues

    To make biodiesel, you need not only the vegetable oil, but an alcohol as well (either ethanol or methanol). The alcohol only
    constitutes about 10% of the volume of the biodiesel. Among the most land-efficient and energy-efficient methods of producing
    alcohol is from hydrolysis and fermentation of plant cellulose. In the early days of the automobile, most vehicles ran on biofuels,
    with Henry Ford himself being a big advocate of alcohol produced from industrial hemp (not to be confused with marijuana). The
    Department of Energy's "Mustard Project" has focused on the prospect of growing mustard for the dual purposes of biodiesel and
    organic pesticide production. Their process focused on alternating mustard crops with wheat. One nice effect of this is that the
    biomass from the mustard (after harvesting the seed ) could be used as the cellulose feedstock for producing alcohol for biodiesel
    production.

    V. Hydrogen?

    Hydrogen as a fuel has received widespread attention in the media of late, particularly ever since the Bush administration
    proclaimed that developing a hydrogen economy would clean our air, and free us of oil dependence. There are many problems with using
    hydrogen as a fuel. The first, and most obvious, is that hydrogen gas is extremely explosive. To store hydrogen at high pressures
    for as a transportation fuel, it is essential to have tanks that are constructed of rust-proof materials, so that as they age they
    won't rust and spring leaks. Hydrogen has to be stored at very high pressures to try to make up for its low energy density. Diesel
    fuel has an energy density of 1,058 kBtu/cu.ft. Biodiesel has an energy density of 950 kBtu/cu.ft, and hydrogen stored at 3,626 psi
    (250 times atmospheric pressure) only has an energy density of 68 kBtu/cu.ft.4 So, highly pressurized to 250 atmospheres, hydrogen's
    volumetric energy density is only 7.2% of that of biodiesel. The result being that with similar efficiencies of converting that
    stored chemical energy into motion (as diesel engines and fuel cells have), a hydrogen vehicle would need a fuel tank roughly 14
    times as large to yield the same driving range as a biodiesel powered vehicle. To get a 1,000 mile range, a tractor trailer running
    on diesel needs to store 168 gallons of diesel fuel. When biodiesel's slightly lower energy density and the greater efficiency of
    the engine running on biodiesel are taken into account, it would need roughly 175 gallons of biodiesel for the same range. But, to
    run on hydrogen stored at 250 atmospheres, to get the same range would require 2,360 gallons of hydrogen. Dedicating that much space
    to fuel storage would drastically reduce how much cargo trucks could carry. Additionally, the cost of the high pressure, corrosion
    resistant storage tanks to carry that much fuel is astronomical.

    There are two main options for producing hydrogen - generating it from water, and extracting it from other fuels. With each case,
    the energy efficiency is well below 100% (i.e. you have to put more energy into separating the hydrogen than the chemical energy the
    hydrogen itself has). I will look at each individually, and then analyze the use of hydrogen as a fuel in general. Currently, most
    hydrogen used industrially is extracted from natural gas through steam reformation. At current usage rates, the United States will
    deplete its projected natural gas reserves in 46 years - or deplete the currently proven reserves in roughly 10 years (we use around
    22.5 trillion cubic feet (tcf) a year, and have a little over 200 tcf of proven reserves). If the use of natural gas for
    transportation (whether directly, or as hydrogen extracted from natural gas) increases dramatically, the time it will take before we
    use up all of our reserves will decrease correspondingly. One of the primary reasons for looking for alternatives to petroleum is to
    decrease our dependence on foreign fuels. If we spend trillions of dollars converting to using natural gas, only to use up our own
    reserves in a decade or two, we would find ourselves back in the exact same position of being dependent on foreign sources.

    Thus, the focus needs to be on renewable fuels that we cannot run out of. For hydrogen, it is only renewable when it is extracted
    from biomass, or when the hydrogen is produced by electrolyzing water using renewable energies (wind, solar, etc.). The option of
    producing it from biomass is not particularly enticing. It can be done through gasification and steam reformation, but with a
    disappointingly low thermal efficiency. The need to compress or liquify (or bind in another form such as a metal hydride) the
    hydrogen for transport and storage further reduces the efficiency, and increases the cost. Biomass can be converted to liquid fuels
    more efficiently, yielding a fuel with far higher energy density, and that can work in existing, affordable vehicles. So, since
    biomass derived hydrogen is less appealing than liquid biofuels, let's consider the option of producing hydrogen through
    electrolysis.

    VI. Hydrogen electrolyzed from water

    The first way to look at a potential transportation fuel is to examine the overall energy efficiency for its production. Ultimately
    we want to know how much energy you get back for each unit of energy you put into developing the fuel - or the Energy Return on
    Investment (EROI). The higher the EROI, the better.

    When discussing hydrogen as a fuel, people usually take a very simplified approach. When used in a fuel cell, the only by-product of
    using hydrogen as a fuel is water. However, that completely ignores the issue of where the hydrogen came from in the first place. It
    is tempting to think that this hydrogen would be produced by electrolyzing water using renewable energy sources, such as wind. To
    see how realistic this approach is, it is important to analyze the overall energy balance, and henceforth the amount of energy that
    would need to be produced for the fuel to be used on a wide scale.

    A common dream from the environmentalist community is having a solar panel on the roof of a home to electrolyze water, producing
    hydrogen for a fuel cell vehicle. It's a nice dream, but not particularly realistic. As a real world example, consider Honda's
    facility in California that requires an 8 kW solar array to produce enough hydrogen to drive one small hydrogen vehicle roughly
    7,500 miles per year8, 9, 10. Such an array could power several homes in California, but is only enough for powering one small car
    half the normal driving range in the US. For an average family with two vehicles that drive an average distance of 15,000 miles per
    year, an array of 32 kW would be needed - considerably more with larger vehicles. A 32 kW array would cost on the order of
    $160,000, and could not be installed just on the rooftop of a single home - it would likely require the south-facing rooftops of at
    least 4-8 houses to power the vehicles from one home (and that's if you live in sunny California - in less sunny regions you'd need
    considerably more). The inefficiency of using electricity to produce and use hydrogen means it makes far more sense to first use
    any newly installed solar or wind power as direct electricity consumption (in houses, businesses, etc.), rather than for hydrogen
    vehicles. A home in California could meet all of its electric needs with perhaps a 2-4 kW array, depending on the household
    efficiency. Yet to power their vehicles it would require a 32 kW array or more. With so few people installing the much smaller
    arrays needed to meet their electrical needs, how likely is it that many would install (or be able to afford to install) a much
    larger array for their vehicles?

    Why does it require so large an array? Look at the efficiency. Electrolysis systems are around 70% efficient (smaller scale
    systems are less efficient, large scale industrial ones are higher - 70% is a rough average). That means that for each unit of
    energy you put in, the amount of recoverable energy in the hydrogen produced is equal to 0.7 units. The hydrogen then needs to be
    compressed to high pressures for storage in fuel tanks (due to the low energy density, hydrogen has to be stored at high pressures
    so that vehicles can have a reasonable range). Compressing the hydrogen is roughly 85% efficient, liquefaction considerably lower.
    I will ignore the cost of transporting hydrogen, the efficiency of which is far lower than transporting biodiesel. Since it is
    highly unlikely that clean solar or wind power would be used for electrolyzing water to make hydrogen (see the above paragraph), I
    will assume that it would use coal or natural gas derived electricity (this could also come from burning biomass). Most such power
    plants operate with efficiencies below 40%, but I will use that very favorable figure.

    So, the hydrogen fuel can be produced with an overall efficiency of 23.8% - or an EROI of 0.238. Current generation fuel cells are
    40-60% efficient. Assuming a very favorable 60% efficiency, that reduces the overall energy return down to 14.28%. That means that
    for each unit of energy in the form of fuel burned to make electricity, only 14.28% of it is usable for powering the electric motor
    in a fuel cell vehicle. Steam reformation of natural gas is a far more likely scenario for hydrogen production, as it can be done
    with roughly a 66% efficiency. Including compression (85%) and use in a fuel cell (a very favorable 60%, with 45% being more
    likely), the overall efficiency is then 33.6% (or a fossil energy balance of 0.336). The problem is natural gas is not a renewable
    resource, and the US could not meet the demand of a nationwide hydrogen economy fed off natural gas. We would simply be replacing
    foreign oil dependence with foreign natural gas dependence. With natural gas being much more expensive (and inefficient) to
    transport over long distances, this isn't a desirable scenario.

    The limited range of hydrogen powered vehicles makes them comparable to electric vehicles in many ways. The energy efficiency,
    however, is completely different. While a hydrogen vehicle would use electricity to electrolyze water to get hydrogen for fuel, an
    electric vehicle uses electricity to charge batteries. Battery charging systems are around 90% efficient, compared to the 70%
    efficiency for electrolysis. Using the charged batteries and an electric motor to propel a car has an efficiency in the 90% range,
    giving electric cars an overall energy efficiency of around 81% (once the electricity is produced, so not counting energy losses at
    that end). By contrast, once the electricity is produced, the efficiency is only around 32%. As can be seen, if the desire is to
    use electricity to power our vehicles, it is far more efficient to do so with electric cars, rather than hydrogen fuel cell
    vehicles. Electric vehicles are also far cheaper, another plus. This is why diesel-electric hybrids with the ability to be
    recharged and operate solely on electric power for a short range are an ideal choice for people who live in cities, or have short
    commutes to work. It allows fairly efficient zero-emissions operation on short commutes, while the diesel engine running on
    biodiesel allows zero net greenhouse gas emissions and practically-zero regulated emissions on longer trips.

    What is the energy efficiency for producing biodiesel? Based on a report by the US DOE and USDA entitled "Life Cycle Inventory of
    Biodiesel and Petroleum Diesel for Use in an Urban Bus"5, biodiesel produced from soy has an energy balance of 3.2:1. That means
    that for each unit of energy put into growing the soybeans and turning the soy oil into biodiesel, we get back 3.2 units of energy
    in the form of biodiesel. That works out to an energy efficiency of 320% (when only looking at fossil energy input - input from the
    sun, for example, is not included). The reason for the energy efficiency being greater than 100% is that the growing soybeans turn
    energy from the sun into chemical energy (oil). Current generation diesel engines are 43% efficient (HCCI diesel engines under
    development, and heavy duty diesel engines have higher efficiencies approaching 55% (better than fuel cells), but for the moment
    we'll just use current car-sized diesel engine technology). That 3.2 energy balance is for biodiesel made from soybean oil - a
    rather inefficient crop for the purpose. Other feedstocks such as algaes can yield substantially higher energy balances, as can
    using thermochemical processes for processing wastes into biofuels (such as the thermal depolymerization process pioneered by
    Changing World Technologies). Such approaches can yield EROI values ranging from 5-10, potentially even higher.


    --------------------------------------------------------------------------------

    The UNH Biodiesel Group is working on improving the technology for growing algae on waste streams for biodiesel production. UNH has
    filed a provisional patent application and is seeking partners to develop the technology. For more information contact:

    Michael Briggs 603-862-2828;
    email [email protected]

 
arrow-down-2 Created with Sketch. arrow-down-2 Created with Sketch.