NdFeB alloy powder - All done by the Magnet Makers.The Method of Manufacture of Neodymium NdFeB Magnets (Neodymium Iron Boron Magnets) is as follows:
In simplified terms, the "Neo" alloy is like a cake mixture, with each factory's recipe for each grade. The resultant melted alloy is then cooled to form ingots of alloy. The alloy ingots are then broken down by hydrogen decrepitation (HD) or hydrogenation disproportionation desorption and recombination (HDDR), and jet milled down in a nitrogen and argon atmosphere to a micron-sized powder (about 3 microns or less in size). This Neodymium powder is then fed into a hopper to allow the pressing of magnets.Methods Of Pressing The Powder
There are three main methods of pressing the powder – axial and transverse pressing. Die pressing requires tooling to make a cavity slightly larger than the necessary shape (because sintering causes shrinkage of the magnet). The Neodymium powder enters the die cavity from the hopper and is then compacted in the presence of an externally applied magnetic field. The external field is either applied parallel to the compacting force (this axial pressing is not so standard) or perpendicular to the compaction direction (called transverse pressing). Transverse pressing gives higher magnetic properties for the Neodymium NdFeB Magnets.
The third method of pressing is isostatic pressing. The NdFeB powder is put into a rubber mould and into a sizeable fluid-filled container, increasing the fluid's pressure. Again, an external magnetising field is present, but the NdFeB powder is compacted from all sides. Isostatic pressing gives the best possible magnetic performance for Neodymium Iron Boron. The methods employed vary depending on the grade of "Neo" required and are decided by the manufacturer.
A solenoid coil set on either side of the compacting powder creates the external magnetising field. The magnetic domains of the NdFeB powder align with the applied magnetising field – the more homogenous the applied field, the more homogenous the magnetic performance of the Neodymium magnet. As the die presses the Neodymium powder, the direction of magnetisation is locked in place – the Neodymium magnet has been given a preferred direction of magnetisation. It is called anisotropic (if no external field were applied, it would be possible to magnetise the magnet in any direction, which is called isotropic, but the magnetic performance would be much lower than that of an anisotropic magnet and is usually confined to bonded magnets).
Rare Earth magnets exhibit uniaxial magnetocrystalline anisotropy, i.e. they have a unique axis crystal structure corresponding with the easy axis of magnetisation. In the case of Nd2Fe14B, the easy axis of magnetisation is the c-axis of the complex tetragonal structure. In the presence of an external magnetising field, it aligns along the c-axis, becoming capable of being fully magnetised to saturation with very high coercivity.
Before the pressed NdFeB magnet is released, it is given a demagnetising pulse to leave it unmagnetised. The compacted magnet is termed a 'green' magnet – it is easy to force to crumble apart, and its magnetic performance is not good. The 'green' Neodymium magnet is sintered to give it its final magnetic properties.
The sintering process is carefully monitored (a strict temperature and time profile have to be applied) and occurs in an inert (oxygen-free) atmosphere (e.g. argon). If oxygen is present, the resultant oxides destroy the magnetic performance of the NdFeB. The sintering process also causes shrinkage of the magnet as the powder fuses together. The shrinkage gives a magnet close to the required shape, but the shrinkage is usually uneven (e.g. a ring may shrink to become an oval).
At the end of the sintering process, a final rapid quench is applied to cool the magnet rapidly. This minimises the unwanted production of 'phases' (in simplified terms, variants of the alloy with poor magnetic properties) that occur below the sintering temperature. A rapid quench maximises the magnetic performance of NdFeB. Because the sintering process causes an uneven shrinkage, the shape of the Neodymium magnet will not be to the required dimensions.
Tolerances and Dimensions
The next stage is to machine the magnets to the required tolerances. Because machining is needed, the Neodymium magnets are made slightly larger when pressed, e.g. larger outer diameter, smaller inner diameter and taller for a ring magnet. Standard magnet dimensional tolerances are +/-0.1mm, although +/-0.05mm is achievable at extra cost. The possibility of even tighter tolerances depends on the shape and size of the magnet and may not be possible.
For note, the Neodymium magnet is rigid. Cutting holes in NdFeB with a standard drill or carbide tip will blunt the drill bit. Diamond-cutting tools (CNC diamond grinding wheels, diamond drills, etc.) and wire-cutting machines (EDM) must be used. The NdFeB swarf powder produced during machining needs to be cooled by liquid. Otherwise, it may spontaneously combust. For Neodymium block magnets, there may be cost savings in using much larger magnet blocks made by isostatic pressing and cutting them into smaller Neodymium blocks of the desired size. This is done for speed and mass production (where enough cutting and grinding machines are present) and is known as "slice and dice". Once the final dimensions for the magnet have been met by machining, the Neodymium magnet is given a protective coating. This is usually a Ni-Cu-Ni coating.
The magnet must be cleaned to remove any swarf/powder from machining. It is then dried thoroughly before being plated. It is imperative that the drying is thorough. Otherwise, water is locked into the plated Neodymium magnet, and the magnet will corrode from the inside out. The plating is very thin, e.g. 15-35 microns for Ni-Cu-Ni (1 micron is 1/1000mm).
The current range of coatings available are as follows:- Nickel-Copper-Nickel (Ni-Cu-Ni) [standard], Epoxy, Zinc (Zn), Gold (Au), Silver (Ag), Tin (Sn), Titanium (Ti), Titanium Nitride (TiN), Parylene C, Everlube, Chrome, PTFE ("Teflon"; white, black, grey, silvery), Ni-Cu-Ni plus Epoxy, Ni-Cu-Ni plus Rubber, Zn plus Rubber, Ni-Cu-Ni plus Parylene C, Ni-Cu-Ni plus PTFE, Tin (Sn) plus Parylene C, Zinc Chromate, Phosphate Passivation and Uncoated (i.e. bare – not recommended but is sometimes required by the customer).
Other coatings may be possible. It is not recommended to use the magnet without a protective layer.
Higher Hci Neodymium NdFeB magnets are said to be better at corrosion resistance, but this does not guarantee safe use when unplated. If necessary, plate the magnets after assembly (this is because any glue would adhere to the plating rather than the NdFeB magnet, so if the plating fails, the magnet becomes free). Removing the plating to allow better glue adhesion is possible. Still, corrosion resistance in the Neodymium magnet may be severely compromised during such a process unless great care is taken during assembly (protective sleeves may be worth considering to ensure the magnets stay in place, e.g. carbon fibre sleeve for rotors).
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